TALLOW AMINE 15 EO
TALLOW AMINE 15 EO
Tallow amine 15 EO = Ethoxylated tallow fatty amine = polyethylene glycol (15) tallow amine = polyoxyethylene (15) tallow amine = Fatty amine ethoxylate = peg-15 Tallow amine =
Amines, tallow alkyl, ethoxylated (15 EO) = CAS No : 61791-26-2
EXAMIN T 150 = Tallow amine 15 EO = TALLOW AMINE ETHOXYLATE, POE-15 = Tallow amine ethoxylate 15 = 15 mole ethoxylate of tallow amine
EXAMIN = Fatty Amine Ethoxylate = Ethoxylated tallow fatty amine
Tallow amine ethoxylates are generally used in agriculture formulation for pesticides and as corrosion inhibitors.
Tallow amine 15 EO functions as wetting agent, solubilizer in textile processing, anti-corrosion agent in oil & gas, and adjuvant in agrochemicals.
Tallow amine 15 EO can be used alone or in combination with other surfactants.
Ethoxylated tallow fatty amine
CAS No : 61791-26-2
Synonyms:
amines, hydrogenated tallow alkyl, ethoxylated (15 mol EO average molar ratio)
polyethylene glycol (15) tallow amine
polyoxyethylene (15) tallow amine
IUPAC names
a-[{2-hydroxyethyl)poly(ethane-1,2-diyloxy}(tallow)amino]-w-(2-hydroxyethyl)poly(ethane-1,2-diyloxy)
Amines, C16-18 alkyl, ethoxylated, 15 EO
AMINES, TALLOW ALKYL, ETHOXYLATED
Amines, tallow alkyl, ethoxylated
Amines, tallow alkyl, ethoxylated (15EO)
Amines, tallow alkyl, ethoxylated (15 EO)
Amines, tallow alkyl, ethoxylated (EO=15)
AMINES, TALLOW ALKYL, ETHOXYLATED 15 EO
Amines, tallow, ethoxylated
ethoxylated alkylamines
Polyethoxylated Tallow Amine
Polyethoxylated tallow amine
Tallow alkylamine ethoxylate
Tallow alkylamine ethoxylate with 15 mol EO
Tallow amine ethoxylate
Ethoxylated tallow fatty amine belong to the category of non-ionic surfactants therefore can be used as emulsifiers and in emulsifier blend formations.
Ethoxylated tallow fatty amine functions as wetting agent and dye leveling agents in textile industries and industrial detergents, solubilizer in textile processing, anti-corrosion agents in oil & gas, and as adjuvant or emulsifiers in agrochemicals.
Ethoxylated tallow fatty amine applications also includes sanitizers, dispersants, stabilizers, and anti-foaming agents.
Fatty amine ethoxylates are considered as a useful an intermediate for the synthesis of anionic surfactants.
They have a wide application.
However, their cationic characteristics have extended their use of these compounds and have brought out novel and valuable means for handling many industrial problems.
The corrosion inhibitory properties of Tallow amine 15 EO they display are very important in petroleum refinery processes.
For instance, a continuous injection of minor amounts of Tallow amine 15 EO into the refinery processes protects metal surfaces from reacting with water, hydrogen chloride and hydrogen sulfide.
In addition, metallic and mineral surface may absorb the cationic surfactant.
Ataman Kimya offers a wide range of ethoxylates of C12 to C22 Fatty Amines like Coco amine, Oleyl Amine, tallow Amine, tallow diamine, Stearyl Amine etc.
Application of Tallow Amine Ethoxylate in Textile Auxiliaries:
Tallow amine 15 EO is used in formulations for textile aids to obtain effects such as an oil in-water emulsifier, moisturizer, emulsifier for quaternary ammonium compounds in water used in softeners, lubricants and anti-static agents for spinning, equalizer for polyamide and polyester dyeing and detergent for washing dyed articles.
Tallow amine 15 Ethoxylate can be used to manufacture textile auxiliaries (e.g. products for dyeing) mineral oil additives, crop protection products and pesticides, raw materials for cosmetics and adhesives.
Tallow amine 15 EO acts simultaneously on polyamide fiber and on dyes, thus permitting a regular assembly of dyes and good distribution of these on the material.
Tallow amine 15 EO is easily removed from polyamide fibers in the hot-water rinsing process, easily soluble in cold water in any proportion, and avoids the formation of rings in dyed fabric.
For dyeing aids Tallow amine 15 EO is useful to employ concentrations of active agents at 0.3% to 2.0% over material weight, where higher concentrations are used to dye in dark colors.
In cases of articles that have accentuated rings or the dyes used have little coverage power, the quantity of Tallow amine 15 EO or Tallow amine 20 EO can be increased to concentrations of 5.0% over material weight, and in the equalizing of defective, poorly joined or out of color dyes, use a bath containing 1.0 to 5.0% of the active agent to the boiling liquid.
Fatty amine ethoxylates
Depending on the degree of ethoxylation, the manufacturing conditions and the pH adjustment, ethoxylates based on primary amines display, to a more or less pronounced extent, the characteristics of cationic surfactans.
This leads to a special surface-active property.
For example, the affinity to various different surfaces that tend to be anionics is particularly high, a property which can be utilised beneficially in the textile and leather processing industries, but also in metal treatment (antistatics, improved grip, hydrophobing, etc.).
Tallow amine 15 EO can also be used as emulsifier, for example in the processing of mineral oil and bitumen.
Amines, tallow alkyl, ethoxylated (15 EO)
Fatty amine ethoxylate are made by ethoxylation of primary fatty amines and combine the wetting, emulsifying and dispersing properties of nonionic and cationic surfactants.
At neutral and acid conditions fatty amine ethoxylates have a positive charge, at alkaline conditions they behave like nonionic surfactants.
Tallow amine 15 EO is used as emulsifiers and dispersing agents for cationic wax emulsions, as wetting agents in sanitary cleaners and crop protection products like soluble liquids of pesticides and as antistatic agents.
Their specific surface active properties make the Tallow Amine Ethoxylate grades a valuable basis and additive for the chemical technical industry.
Tallow Amine Ethoxylate can be used to manufacture textile auxiliaries (e.g. products for dyeing), as mineral oil additives, in crop protection products and pesticides, and as raw materials for cosmetics and adhesives Tallow Amine Ethoxylate grades can be combined with all types at nonionic and cationic surfactants, and are compatible with anionic products on a case-by-case level.
Tallow Amine Ethoxylate grades are resistant to most chemicals at typical concentrations used and insensitive to water hardness.
Ethoxylated fatty amines are nonionic surfactants used as an emulsifier and in formulating emulsifier blends.
Tallow amine 15 EO is used as a wetting agents, dispersants, stabilizers, sanitizers and defoaming agents.
End applications of Tallow amine 15 EO include agrochemical emulsifiers, industrial cleaners, metal cleaners, textiles, paper de-inking, drilling products and detergents.
Tallow amine 15 EO is used as an intermediate for the synthesis of anionic surfactants.
Fatty amines ethoxylates have many uses, primarily as nonionic surfactants in various formulations both, industrial & domestic.
Tallow amine 15 EO is also used as cleaning agents, antistatic agents, dispersants or emulsifiers, in textile formulations, corrosion inhibitors in metal & emulsifiers, adjuvant in agrochemical formulations oil field chemicals, fabric softeners, petroleum additives and for applications in textile and leather processing.
Industries
Leather & Textiles , Other Industries , Chemical Manufacturing
Applications
Non-ionic Surfactants , Anti-corrosion , Wetting & Leveling Agents
Tallow amine 15 EO is a medium EO range tallow amine ethoxylate.
Tallow amine ethoxylate grades can be combined with all types at nonionic and cationic surfactants, and are compatible with anionic products on a case-by-case level.
Tallow amine ethoxylate grades are resistant to most chemicals at typical concentrations used and insensitive to water hardness.
Tallow amine 15 EO
AMINE ETHOXYLATE
Tallow amine 15 EO is a medium EO range tallow amine ethoxylate.
Benefits
Tallow amine 15 EO is insensitive to water hardness
Tallow amine 15 EO can be combined with all types at nonionic and cationic surfactants
Tallow amine 15 EO is resistant to most chemicals at typical concentrations used
Product class: Amine ethoxylate
REACH status: Exempted due to polymer status
Cloud point method: –
Cloud point [°C]:-
Product composition: Tallow fatty amine with 15 EO
Active content (ca.): 100%
Appearance: Liquid
Water content :
HLB (calc.): –
Composition
Tallow fatty amine ethoxylate with 15 mol EO
Product properties *)
Concentration [%]: Approx. 100
Appearance at 20 °C: yellowish to brownish liquid
Gardener colour: 6 – 10
pH, 1% aqueous solution (20 °C): 10 – 11
Solubility at 20 °C
1 % in water: clear
1 % in mineral oil: turbid
1 % in xylene: clear
1 % in glycol: clear
Density at 50 °C [g/cm³]: 1.00 – 1.02
Viscosity at 50 °C [mPas]: approx. 50
Refractive index at 50 °C: approx. 1.460
Pour point [°C]: approx. – 5
Flash point [°C]: > 200
Alkali value [mg KOH/g]: 59.7 – 61.7
Lime soap dispersing power
–
Surface tension [g/l]
–
Dip-wetting ability 100 s at 25 °C
–
Fatty amine ethyloxylates
The surface-active fatty amine ethoxylates are obtained by the action of ethylene oxide on fatty amine.
The reaction can be represented in summary simplified form by the following general equation:
Fatty amine Ethylene oxide Fatty amine ethoxylate
x + y = n number of molecules of ethylene oxide added
As a result of the addition of ethylene oxide to the fatty amines, dihydric alcohols with terminal hydroxyl groups are produced.
Under suitable conditions further reactions with these are possible.
Moreover, the bridge nitrogen can be quaternized.
Fatty amine ethoxylates are in principle basic in nature, form salts with acids and have an alkaline reaction in aqueous solution.
In view of their surface activity they must therefore be classified with the cationic compounds and, like them, prove to be substantive.
Nevertheless, they often behave like nonionic surfactants towards many indicators and also in other applications, and all the more so the longer the added ethylene oxide chain is.
Their physical and chemical properties, and especially the surface-active ones, are determined largely by the ratio of the hydrophobic fatty amine radical to the hydrophilic solubilizing polyglycol chains in the molecule.
The length of the polyglycol chains is indicated by the number of molecules of ethylene oxide added per molecule of fatty amine and is also known as degree of ethoxylation.
Since both the type of initial fatty amine and the amount of ethylene oxide can be chosen arbitrarily, there are two possibilities for modifying the hydrophilic/hydrophobic balance.
Both have been employed in producing Tallow Amine Ethoxylate product range.
This consists of four groups, each of which is based on a different fatty amine and is distinguished by corresponding code letters:
C = Coconut fatty amine
saturated C8-C18 fatty amines, predominantly C12-C14
O = Oleylamine
predominantly unsaturated C18 fatty amines
S = Stearylamine
saturated C16-C18 fatty amines
T = Tallow fatty amine
saturated and unsaturated C16-C18 fatty amines
A multistage ethoxylation series is available for each of these amines, and the number of added molecules of ethylene oxide is expressed by an additional suffix, e.g. 080 for 8, 150 for 15 and 250 for 25 moles of ethylene oxide per molecule of fatty amine.
The last zero in all suffixes indicates that all grades contain practically 100 % active substance.
Common degrees of ethoxylation areTallow amine Ethoxylate grades with 2, 5, 8, 20 and 25 moles of ethylene oxide.
If for special purposes a narrower range is required, this can easily be achieved by formulating corresponding blends of neighboring products.
Sometimes, however, blends of more distant products produce even better effects.
The procedure is to use the usual mixing rule and to employ the amine numbers as a basis for calculation.
Moreover, when entire production batches are taken, any degrees of ethoxylation can be produced.
To obtain completely homogeneous blends, it is preferable to employ temperatures of 50 – 60°C.
It is recommended that this temperature should be also maintained when aqueous dilutions are produced.
In certain concentration ranges (usually between 70 and 40 % active substance) the occurrence of gelatinous hydrates, which are slow to dissolve in cold water, is avoided.
In suitable cases the gel state can be eliminated by adding solubilizers (alcohols, glycols, etc.).
These are also appropriate if stable, non-flammable, higher dilutions are to be produced from products that form a turbid solution.
In principle the solubility in water rises with increasing degree of ethoxylation.
The slightly ethoxylated products are only moderately dispersible at room temperature and therefore form turbid solutions resembling emulsions.
The medium and higher-ethoxylated products dissolve to form a clear solution.
On the other hand, the solubility in water decreases with rising temperature.
Therefore turbidity can occasionally occur even in inherently clear solutions, for example if the recommended working temperature of 50 – 60°C is maintained when dilutions are prepared.
This is a reversible physical phenomenon that normally impairs neither further processing nor subsequent use.
The solutions become clear again as they cool. Higher-ethoxylated compounds display no turbidity in aqueous solution up to boiling point.
However, with these too the temperature limit is depressed to a greater or lesser extent by large quantities of electrolytes, especially neutral salts or alkalis.
Just like the fatty amines, Tallow amine Ethoxylate grades, especially in concentrated form, have a corrosive effect on the skin and mucous membranes.
The appropriate protective measures must therefore be taken when the products are processed.
EXAMIN grades can be combined unreservedly with nonionic and other cationic surface-active substances.
Compatibility with anionic products must however be checked in each case.
Tallow amine Ethoxylate grades are largely resistant to most chemicals in the common application concentrations and are practically indifferent to hard water.
Their specific surface-active properties make them valuable raw materials and mixing components for the chemicaltechnical industry.
They are suitable e.g. for the manufacture of dyeing and other textile auxiliaries, mineral oil additives, crop protection products, pesticides, cosmetic starting materials and bonding agents, details of which are beyond the scope of this data sheet.
Product use
Tallow amine Ethoxylate grades can be combined with all types at nonionic and cationic surfactants.
The compatibility with anionic products must be checked for each case.
Tallow amine Ethoxylate grades are resistant to most chemicals at typical concentrations used.
Tallow amine Ethoxylates are insensitive to water hardness.
Their specific surface active properties make Tallow amine Ethoxylates valuable bases and additives for the chemical technical industry.
Tallow amine Ethoxylates can be used to manufacture textile auxiliaries (e.g. products for dyeing) mineral oil additives, crop protection products and pesticides, raw materials for cosmetics and adhesives.
DESCRIPTION
Examin T line is comprised of nonionic surfactants obtained from the reaction of tallow fatty amines with ethylene oxide in several degrees of ethoxylation.
The product line is:
Product Chemical Description CAS No.
EXAMIN T 50: Tallow fatty amine with 5 EO ; CAS: 61791-26-2
EXAMIN T 100: Tallow fatty amine with 10 EO ; CAS: 61791-26-2
EXAMIN T 120: Tallow fatty amine with 12 EO ; CAS: 61791-26-2
EXAMIN T 150: Tallow fatty amine with 15 EO ; CAS: 61791-26-2
EXAMIN T 200: Tallow fatty amine with 20 EO ; CAS: 61791-26-2
Cas: Chemical Abstracts Society
APPLICATIONS
EXAMIN line fatty amine ethoxylates are nonionic surfactants for general use, also used in formulations for applications in acid mediums where the product’s aminic group is protoned and the molecule exhibits cationic surfactant proprieties.
EXAMIN T 50, EXAMIN T 100, EXAMIN T 120 and EXAMIN T 150 have good solubility in water, however dissolution demands care such as heating, shaking and adding the product to water in small portions.
The direct addition of water may cause product jellification.
EXAMIN T 200 does not have this problem and dissolution in water is easier.
Textile Auxiliaries
EXAMIN products are used in formulations for textile aids to obtain effects such as an oil in-water emulsifier, moisturizer, emulsifier for quaternary ammonium compounds in water used in softeners, lubricants and anti-static agents for spinning, equalizer for polyamide and polyester dyeing and detergent for washing dyed articles.
EXAMIN products act simultaneously on polyamide fiber and on dyes, thus permitting a regular assembly of dyes and good distribution of these on the material.
The product is easily removed from polyamide fibers in the hot-water rinsing process, easily soluble in cold water in any proportion, and avoids the formation of rings in dyed fabric.
For dyeing aids it is useful to employ concentrations of active agents at 0.3% to 2.0% over material weight, where higher concentrations are used to dye in dark colors.
In cases of articles that have accentuated rings or the dyes used have little coverage power, the quantity of EXAMIN T 150 or EXAMIN T 200 can be increased to concentrations of 5.0% over material weight, and in the equalizing of defective, poorly joined or out of color dyes, use a bath containing 1.0 to 5.0% of the active agent to the boiling liquid.
CAS number
61791-26-2
Chemical Name:
Tallow amine ethoxylate (3-50EO)
Synonyms:
TAM 105 ; Tallow alkyl amines, ethoxylated ; Toximul TA 10 ; Toximul TA 15 ; Toximul TA2 ; Toximul TA 5 ; Toximul TA 6 ; Trymeen 6606 ; Trymeen 6607 ; Trymeen TAM ; VaronicT 202 ; Varonic T 205 ; Varonic T 210 ; Varonic T 216 ; Varonic T 220 ; Varonic T220D ; Weedmaster CT Surfactant ; Witcamine 405 ; Witcamine 6606 ; Witcamine TAM105 ; Witcamine TAM 45 ; Witconol TD 1407 ; Tam 15 ; Teric 17M2 ; Teric 204 ; Terwet 3780 ; Toximul 8362 ; Agnique Tam5 ; Alkaminox T 12 ; Alkaminox T 2 ; Amiet 502 ; Amiladin D ; Amines, tallow, ethoxylated ; Amines, tallow, polyethoxylated ; Atlas G 3762 ; Atlas G 3780644 ; Atlas G 3780A ; Atmer 261 ; Berol 392 ; Chemeen T 5 ; Crisomin T 15 ; Crodamet T 15 ; Entry II ; Ethokem ; Ethomeen T ; Ethomeen T 12 ; Ethomeen T 15 ; Ethomeen T 16 ; Ethomeen T20 ; Ethomeen T 25 ; Ethomeen T 27 ; Ethomeen T 30 ; Ethomeen T 40 ; Ethomeen T 70 ; Ethox TAM 15 ; Ethox TAM 2 ; Ethox TAM 20 ; Ethox TAM 5 ; Ethoxamine SF 11 ; Ethoxamine SF 15 ; Ethoxylated tallow alkyl amines ; Ethoxylated tallow amines ; Ethylan TT 05 ; Ethylan TT 15 ; Ethylan TT 203 ; Ethylan TT 40 ; Frigate ; G 3780A ;Tallow amine Ethoxylate T ;Tallow amine Ethoxylate T 020 ;Tallow amine Ethoxylate T 050 ;Tallow amine Ethoxylate T 080 ; Tallow amine 10 EO ;Tallow amine EthoxylateT 120 ;
EXAMIN T 150 ;Tallow amine Ethoxylate T 200 ;Tallow amine Ethoxylate T 200NF ;Tallow amine Ethoxylate T 250 ; HostastatFA 38 ; Hyspray ; Icomeen T 15 ; Icomeen T 2 ; Jeetox T 2 ; KFG 597C ; Katapol PN430 ; Katapol PN 530 ; Katapol
PN 730 ; Katapol VP 532 ; Kemamine AS 974-1 ; MON0818 ; Mazeen T 2 ; Meteor ; Nalco NM 159 ; Newcol TA 420 ; Nissan Nymeen T 2-202 ; Nissan Nymeen T 2-230 ; Nissan Nymeen T 2-260 ;
Noramox S ; Noramox S 1 ; Noramox S11 ; Noramox S 2 ; Noramox S 5 ; Noramox S 7 ; Prevocell 1618/3 ; Rhodameen IT50/46 ; Rhodameen PN 430 ; Rhodameen T 12/90 ; Rhodameen T 15 ;
Rhodameen T 50 ; Rhodameen T 7 ; Rhodameen VP 532 ; Rhodameen VP 532SPB ; Surfonic AGM 510 ; Surfonic T 10 ; Surfonic T 15 ; Surfonic T 2 ; Surfonic T 20 ; Surfonic T 5 ; Surfonic T 6 ;
PEG-N tallowamine ; Amines, tallow alkyl,ethoxylated
FATTY AMINE ETHOXYLATED
Fatty amine ethoxylates are non-ionic surface-active agents manufactured by addition of different moles of ethylene oxide to fatty amines producing a range of ethoxlated molecules.
Fatty amine ethoxylates, range from liquid, to pasty solids. This nature depends on the length of fatty alkyl chain and the apparent number of ethoxyl groups.
These Non-ionic surfactants contain both hydrophobic tail portion and hydrophilic polar head groups.
Therefore, they tend to dissolve in both aqueous and oil phase reducing the surface tension of liquids.
Using more hydrophilic groups like EO brings about better solubility in water since more hydrogen bonding exists.
These Fatty amine ethoxylates do not dissociate in solution i.e. non-ionic in solution thus do not form charged particles with residual electrical charge.
This means that these non-ionic Fatty amine ethoxylate surfactants will work well in hard water and at low temperatures.
Moreover, they exhibit more stability in acidic and alkali solution plus miscibility with other surfactants.
Further, since these Fatty amine ethoxylates are nonionic surfactants they exhibit excellent foam properties, outstanding solvency and absolute chemical stability providing overall good detergency properties.
Raw Fatty amines like tallow amine, tallowdiamine, lauryl amine, cocoamine, stearyl amine and oleyl amine are routinely converted to fatty amine ethoxylate.
Amine ethoxylates are nonionic surfactants formed from the reaction of alkyl amine with ethylene oxide.
These ethoxylates play an important role in oil & gas and agrochemicals, as well as, in textile processing.
The ethoxylates act as the wetting agent, solubilizer, anti-corrosion agent, and adjuvant.
Ataman’s product line includes amine ethoxylates based on cocoamine, tallow amine, and other alkyl amines reacted with various moles of ethylene oxide.
OTHER PRODUCTS OF ATAMAN THAT MIGHT BE OF INTEREST:
SURFACTANTS (ANIONIC)
Sodium Lauryl Sulfate Powder
Sodium 2-Ethylhexyl Sulfate 40%
Disodium Laureth Sulfosuccinate 40%
Disodium Cocamido MEA Sulfosuccinate 40%
Sodium Dioctylsulfosuccinate 70%
Sodium Lauroyl Sarcosinate 30%
SURFACTANTS (AMPHOTERIC)
CAPB 35%
CAPB 45%
Disodium Cocoamphodiacetate 50%
Disodium Cocoamphodipropionate 40%
Disodium Cocoamphodipropionate 70%
SURFACTANTS (NONIONIC)
Cocamide MEA
Cocamide DEA
PEG-7 Castor Oil
PEG-11 Castor Oil
PEG-20 Castor Oil
PEG-25 Castor Oil
PEG-35 Castor Oil
PEG-40 Castor Oil
PEG-40 Hydrogenated Castor Oil
Fatty Alcohol C16C18 EO 5
Fatty Alcohol C16C18 EO 20
Fatty Alcohol C16C18 EO 25
Fatty Alcohol C16C18 EO 50
Fatty Alcohol C16C18 EO 80
Oleic Acid EO 7
Coco Amine EO 5
Coco Amine EO 10
Oleyl Amine EO 2
Oleyl Amine EO 10
Oleyl Amine EO 20
Tallow Amine EO 2
Tallow Amine EO 5
Tallow Amine EO 10
Tallow Amine EO 15
Tallow Amine EO 20
Tallow Amine EO 25